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Direct Asymmetric Catalytic Oxidation of Ketones to α-Hydroxy Ketones Using a Chiral Bimetallic Pd(II) Complex

Conference: 
The Fifth Palestinian International Chemistry Conference
Authors: 
Othman A. Hamed
Emad M. Hamed
Patrick M. Henry
Daniel P. Becker
Abstract: 

Chiral bimetallic palladium (II) complex B was used in a catalytic air oxidation process to convert ketones directly into optically active α-hydroxyketones. The reaction was carried out in an aqueous solution of THF or dioxane, and in the presence of a catalytic amount of an acid. The enantiomeric excess (e.e.) of produced

Full Text: 
PDF icon Direct Asymmetric Catalytic Oxidation of Ketones to α-Hydroxy Ketones Using a Chiral Bimetallic Pd(II) Complex